Water Quality Monitoring

USGS Gauging Station at Greensboro, MD (01491000) 

History | Hydrology & Density of the Choptank | Photo Archive

Only a small fraction of the Choptank River basin is gauged (Fig. A5). The USGS gauging station at Greensboro MD integrates the hydrology of 18% of the Choptank basin (Lee et al 2000) and was established in 1948 (link to USGS site). As part of an ongoing program which monitors water quality in the Choptank River Basin, we have been regularly collecting water samples since 1979 from the USGS gauging station on the river near Greensboro, MD. Samples have been analyzed for pH, conductivity, and concentrations of ammonium (NH4), phosphate (PO4), nitrite + nitrate (NO2 + NO3), total nitrogen (TN), and total phosphorus (TP). Analysis of the first eleven years of these data is available in Fisher et al (1998).

Greensboro Sampling History (back to top)

In October 1979 we began an intensive monitoring program at the USGS gauging station. Samples were collected manually by Robert and Edna Hanley, who lived near the gauge site, and we picked up and processed the samples monthly. This program continued until 2000, when the Hanleys retired and relocated.

On May 31, 2000, in a joint program with USGS, an ISCO 6700 autosampler was installed in the USGS gauging station and the sampler now takes daily samples composited on a weekly basis. In addition, USGS uses a modem on the sampler to take discrete samples 15-25 times per year.

Hydrology and density of the Choptank River (back to top)

Inter Annual variations in discharge at Greensboro are caused by variations in rainfall (Fig. 1). Discharge varies by a factor of 3-4 between dry and wet years, and there are cycles of wet and dry years with about a 5-10 year period. During 1949-2001, there are no long term trends in discharge; however, during the Bay Program's monitoring record, which began during a dry year (1985), there is a significant positive trend in discharge which is caused only by the timing of the starting year.

2002 was unusually dry, especially during the end of the summer. Very low rainfall and persistently high temperature resulted in extremely low flows that were ~10% of long term means for July and August (Fig. 2).

N and P concentrations vary considerably with stream flow. Figure 3 shows a time series of rainfall data in fall 1982 (black bars in top panel) which gradually saturated soils, and the third storm on day 76 (Dec 15) caused a major increase in stream flow (solid circles in top panel). At the peak of the flow event, nitrate and TN concentrations (middle panel) were depressed by overland flow of rain water with relatively low N diluting groundwater with high N, especially nitrate content. In contrast, P concentrations (lower panel) increased with flow. The small panels at the bottom show the concentrations of N and P as a function of discharge. The high concentration of nitrate in groundwater are caused by fertilizer applications and leaching from septic systems (Fig. 4).

There are significant trends in water quality at the Choptank station. Nitrate, in particular, has been increasing over the period of record (Fig. 5). In the 1960's, nitrite and nitrate concentrations (dominated by nitrate, NO3) was 30-70 uM (0.42-0.98 mg NO3-N/L). In the late 1990's, nitrate concentrations were 70-90 uM (0.98-1.26 mg NO3-N/L), about a 50 percent increase compared to 30 years earlier.

 

Waste water treatment Plants (back to top)

There are eleven waste water treatment plants in the Choptank River basin licensed by Maryland Department of the Environment (Table 1). Of these eleven, the two largest, Cambridge and Easton, discharge __% of the total waste water discharge. All of the plants in Table 1 have secondary treatment (removal of biosolids and biological oxygen demand, but most of the original nutrients remain in solution), and several have-or are adding-tertiary treatment to remove N and P.

Sewage effluent samples have been collected from the two largest Choptank treatment plants, Cambridge and Easton, since 1984. At that time, there was only annual analysis of effluent. These plants discharge treated sewage into the river and Councell Creek (see map). The wastewater samples which we collect are processed for both TN and TP measurements.

 

Atmospheric deposition of C, N, and P